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Brine Migration and Heat Flow

Brine is known to migrate in sea ice, influenced by gravity, by internal pressure changes and by temperature gradient (Kingery and Goodnow, 1963; Jones, 1973; Hoekstra et al., 1965). Brine pockets move slowly towards higher temperatures, and brine moves downwards. Both directions are the same for most of our data.

Brine movement, excluding brine expulsion by pressure changes and stress cracking, is associated with latent heat of freezing and melting effects, as ice remains where brine once was. The contribution to heat flux, of pockets of brine moving with velocity W is tex2html_wrap_inline330 , where tex2html_wrap_inline332 is the volume fraction of sea ice occupied by brine, and tex2html_wrap_inline334 and L are the density and latent heat respectively of pure water. Pure water values are used because most of the salts remain in the brine as it migrates.

Then the heat equation is modified to

equation61

In the following, we consider what movement of brine is needed to contribute significantly to heat flow, say by the amount 2 W m tex2html_wrap_inline338 when tex2html_wrap_inline340 Cm tex2html_wrap_inline186 . This is 5% of the 40 Wm tex2html_wrap_inline338 conducted by ice with a thermal conductivity 2 Wm tex2html_wrap_inline186   tex2html_wrap_inline156 C tex2html_wrap_inline186 at this temperature gradient. Using tex2html_wrap_inline352  kg m tex2html_wrap_inline354 , L=350 kJ kg tex2html_wrap_inline186 , and tex2html_wrap_inline360 corresponding to tex2html_wrap_inline362 C gives

equation78

so that the peak velocity of brine pockets (when temperature gradients are high) would need to be about tex2html_wrap_inline364  m s tex2html_wrap_inline186 , to contribute this heat flow. This velocity is reasonable in its implications for desalination of sea ice. It corresponds to a peak salt flux of tex2html_wrap_inline368  kg m tex2html_wrap_inline338 s tex2html_wrap_inline186 , comparable to the gravity drainage salt fluxes observed by Kingery and Goodnow (1963). So total salt balance arguments are consistent with the idea that brine movement may contribute significantly to heat flux. What is less clear is the exact nature of the mechanism that is responsible for the brine movement. Possible mechanisms are explored in the following sections.


next up previous
Next: Diffusion-Driven Migration Up: Nonlinear Thermal Transport and Previous: Analysis of Data

Mark McGuinness
Tue Apr 11 17:10:31 NZST 2000